A research group led by Prof. WANG Suli and Prof. SUN Gongquan from the Dalian Institute of Chemical Physics (DICP) of the Chinese Academy of Science (CAS) constructed uneven phosphoric acid interfaces within the nanofiber electrode for the high temperature polymer electrolyte fuel cells (HT-PEFCs), which reduce the resistance of oxygen transport.
This study was published in Science Advances on January 25.
Manufacture, storage, and delivery of the highly purified hydrogen are challenges for the commercialization of PEFCs. Elevated temperature (>150oC) can realize PEFCs fed with hydrogen-rich product reformed from liquid fuels, which is expected to solve the problem of fuel storage and transportation.
However, insufficient performance with relatively inferior specific power limits the widespread application of HT-PEFCs. Different from the low temperature-PEFCs (LT-PEFCs), liquid phosphoric acid (PA) is adopted to form a proton-conductive phase and electrochemical interfaces within the porous electrodes of HT-PEFCs, leading to ultrahigh mass transport resistance and catalyst poisoning.
In order to reduce mass transport resistance for HT-PEFCs, the researchers designed uneven PA interfacial layers with dispersed droplets by constructing the fibrous electrode architecture. Due to the ultra-hydrophobic nature of the nanofiber networks, PA agglomeration occured as forms of non-infiltration droplets in the size of micrometer scale, which is different from the traditional immersion model of PA under working circumstances.
This uneven distribution of PA provided reduced thickness and coverage of the PA layers on the surface of catalyst within the porous electrode, leading to a 32% decrease in oxygen interfacial transport resistance and much enhanced electrochemical surface area compared to that of the conventional one.
As a result, the peak power density of the fibrous electrode reached 414 mW cm-2, 28% greater than that of the conventional porous electrode, demonstrating great application potential of HT-PEFCs.
This work was supported by the National Nature Science Foundation of China, the National Key Research and Development Program of China, the Foundation of the Key Laboratory of CAS, and DICP.