Research News

Single-atom-driven Dynamic Carburization Boosts CO2 Conversion during Long-term Reaction

Posted: 2022-11-18

Single-atom catalysts (SACs) are a new type of heterogeneous catalysts due to their ultimate efficiency of metal atom use and unique activity/selectivity compared with nanoparticle catalysts.

Current studies in SACs focus on the specific activity and selectivity of the single active sites, the distinct reaction mechanisms in real reactions are still unclear.

Recently, a research group led by Prof. ZHANG Tao and Assoc. Prof. YANG Bing from the Dalian Institute of Chemical Physics (DICP) of the Chinese Academy of Sciences (CAS), in collaboration with Prof. ZHU Beien from Shanghai Institute of Applied Physics of CAS, revealed a novel mechanism of SACs in real reactions.

"Besides providing single active sites, the Pd SACs could also promote the dynamic carburization of FeOx surface over long-term reaction during CO2 conversion, leading to remarkably enhanced reverse water-gas shift activity and CO selectivity," said YANG.

This study was published in Chem on September 12.

Single-atom-driven dynamic carburization over Pd1-FeOx SACs (Image by YANG Bing)

The researchers found that Pd1- FeOx SACs promoted sustained carburization of FeOx surface over long-term reaction with increasing reverse water gas shift activity (from 17% to 28%) and CO selectivity (>98 %). By contrast, Pd-NPs-FeOx (~4nm Pd nanoparticles) possessed excellent stability during the entire time-on-stream test with CO2 conversion remaining at ~20%.

Moreover, they reported an unexpected role of Pd1 single atoms. The Pd single atoms not only provided single active sites by activating surface oxygen species at the initial stage, but also promoted dynamic carburization of FeOx surface to achieve the highly active Fe5C2 phase and diminish active barriers to 27.7 kJ/mol over long-term reaction, far beyond that of previously reported Fe-based catalysts. In comparison, carburization was inhibited on Pd nanoparticle catalyst by a rapid FeOx encapsulation during the initial reaction via strong metal-support interaction.

"This work improves the general understanding of the reaction mechanism of SACs," said YANG. "The role of single atoms is not only to provide single active sites but to promote the formation of the highly active phase of heterogenous catalysts during real reactions, and both roles should be considered in the rational design."

The above work was supported by the National Key R&D Program of China, the National Natural Science Foundation of China, the CAS Project for Young Scientists in Basic Research, and the Innovation Grant from DICP. (Text by DU Pengfei and YANG Bing)