Chemistry and Chemical Engineering
QIAO Botao
Title: Professor
Subject: Industrial Catalysis
Phone: 0411-84379416
Email: bqiao@dicp.ac.cn
Website:
Research Interests
Heterogeneous catalysis, nanomaterial, energy conversion, environmental catalysis, carbon resource molecule transformation; single-atom catalysis; metal-support interaction
1. single-atom catalysts and their application in energy and environmental catalysis.
2. novel strong metal-support interaction and their mechanism and applications in heterogeneous catalysis.
Biography
Botao Qiao received his Ph.D. degree in Physical Chemistry from Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, in 2008. After 3 years’postdoctoral research in professor Tao Zhang's group at Dalian Institute of Chemical Physics, he joined the same group and was promoted to associated professor in 2011. He was visiting scholar and did postdoctoral research at Arizona State University in 2012-2015. And then he returned to the Prof. Zhang's group and was promoted as a full professor in 2017.
He has published near 100 peer-reviewed papers including Chem. Rev., Nat. Chem., Sci. Adv., J. Am. Chem. Soc., Chem , Nat. Commun., Angew. Chem. In. Ed. with over 13000 citations.
Honors and Awards
Publications
1. Yang, J.; Huang, Y.; Qi, H.; Zeng, C.; Jiang, Q.; Cui, Y.; Su, Y.; Du, X.; Pan, X.; Liu, X.; Li, W.; Qiao, B.; Wang, A.; Zhang, T., Modulating the strong metal-support interaction of single-atom catalysts via vicinal structure decoration. Nature Communications 2022, 13 (1), 4244.
2. Guo, Y.; Huang, Y.; Zeng, B.; Han, B.; Akri, M.; Shi, M.; Zhao, Y.; Li, Q.; Su, Y.; Li, L.; Jiang, Q.; Cui, Y.-T.; Li, L.; Li, R.; Qiao, B.; Zhang, T., Photo-thermo semi-hydrogenation of acetylene on Pd1/TiO2 single-atom catalyst. Nature Communications 2022, 13 (1), 2648.
3. Zhang, Y.; Zhang, J.; Zhang, B.; Si, R.; Han, B.; Hong, F.; Niu, Y.; Sun, L.; Li, L.; Qiao, B.; Sun, K.; Huang, J.; Haruta, M., Boosting the catalysis of gold by O2 activation at Au-SiO2 interface. Nature Communications 2020, 11 (1), 558.
4. Yang, J.; Peng, M.; Ren, G.; Qi, H.; Zhou, X.; Xu, J.; Deng, F.; Chen, Z.; Zhang, J.; Liu, K.; Pan, X.; Liu, W.; Su, Y.; Li, W.; Qiao, B.; Ma, D.; Zhang, T., A Hydrothermally Stable Irreducible Oxide-Modified Pd/MgAl2 O4 Catalyst for Methane Combustion. Angew. Chem. Int. Ed. Engl. 2020, 59 (42), 18522-18526.
5. Liu, K.; Zhao, X.; Ren, G.; Yang, T.; Ren, Y.; Lee, A. F.; Su, Y.; Pan, X.; Zhang, J.; Chen, Z.; Yang, J.; Liu, X.; Zhou, T.; Xi, W.; Luo, J.; Zeng, C.; Matsumoto, H.; Liu, W.; Jiang, Q.; Wilson, K.; Wang, A.; Qiao, B.; Li, W.; Zhang, T., Strong metal-support interaction promoted scalable production of thermally stable single-atom catalysts. Nature Communications 2020, 11 (1), 1263.
6. Li, X.; Lin, J.; Li, L.; Huang, Y.; Pan, X.; Collins, S. E.; Ren, Y.; Su, Y.; Kang, L.; Liu, X.; Zhou, Y.; Wang, H.; Wang, A.; Qiao, B.; Wang, X.; Zhang, T., Controlling CO2 Hydrogenation Selectivity by Metal-Supported Electron Transfer. Angew. Chem. Int. Ed. Engl. 2020, 59 (45), 19983-19989.
7. Li, T.; Chen, F.; Lang, R.; Wang, H.; Su, Y.; Qiao, B.; Wang, A.; Zhang, T., Styrene Hydroformylation with In Situ Hydrogen: Regioselectivity Control by Coupling with the Low-Temperature Water–Gas Shift Reaction. Angew. Chem. Int. Ed. 2020, 59 (19), 7430-7434.
8. Lang, R.; Du, X.; Huang, Y.; Jiang, X.; Zhang, Q.; Guo, Y.; Liu, K.; Qiao, B.; Wang, A.; Zhang, T., Single-Atom Catalysts Based on the Metal–Oxide Interaction. Chem. Rev. 2020, 120 (21), 11986-12043.
9. Han, B.; Guo, Y.; Huang, Y.; Xi, W.; Xu, J.; Luo, J.; Qi, H.; Ren, Y.; Liu, X.; Qiao, B.; Zhang, T., Strong Metal-Support Interactions between Pt Single Atoms and TiO2. Angew. Chem. Int. Ed. Engl. 2020, 59 (29), 11824-11829.
10. Du, X.; Huang, Y.; Pan, X.; Han, B.; Su, Y.; Jiang, Q.; Li, M.; Tang, H.; Li, G.; Qiao, B., Size-dependent strong metal-support interaction in TiO2 supported Au nanocatalysts. Nature Communications 2020, 11 (1), 5811.
11. Zhao, S.; Chen, F.; Duan, S.; Shao, B.; Li, T.; Tang, H.; Lin, Q.; Zhang, J.; Li, L.; Huang, J.; Bion, N.; Liu, W.; Sun, H.; Wang, A.-Q.; Haruta, M.; Qiao, B.; Li, J.; Liu, J.; Zhang, T., Remarkable active-site dependent H2O promoting effect in CO oxidation. Nature Communications 2019, 10 (1), 3824.
12. Lang, R.; Xi, W.; Liu, J.-C.; Cui, Y.-T.; Li, T.; Lee, A. F.; Chen, F.; Chen, Y.; Li, L.; Li, L.; Lin, J.; Miao, S.; Liu, X.; Wang, A.-Q.; Wang, X.; Luo, J.; Qiao, B.; Li, J.; Zhang, T., Non defect-stabilized thermally stable single-atom catalyst. Nature Communications 2019, 10 (1), 234.
13. Ding, S.; Guo, Y.; Hülsey, M. J.; Zhang, B.; Asakura, H.; Liu, L.; Han, Y.; Gao, M.; Hasegawa, J.-y.; Qiao, B.; Zhang, T.; Yan, N., Electrostatic Stabilization of Single-Atom Catalysts by Ionic Liquids. Chem 2019, 5 (12), 3207-3219.
14. Akri, M.; Zhao, S.; Li, X.; Zang, K.; Lee, A. F.; Isaacs, M. A.; Xi, W.; Gangarajula, Y.; Luo, J.; Ren, Y.; Cui, Y.-T.; Li, L.; Su, Y.; Pan, X.; Wen, W.; Pan, Y.; Wilson, K.; Li, L.; Qiao, B.; Ishii, H.; Liao, Y.-F.; Wang, A.; Wang, X.; Zhang, T., Atomically dispersed nickel as coke-resistant active sites for methane dry reforming. Nature Communications 2019, 10 (1), 5181.
15. Tang, H.; Su, Y.; Guo, Y.; Zhang, L.; Li, T.; Zang, K.; Liu, F.; Li, L.; Luo, J.; Qiao, B.; Wang, J., Oxidative strong metal–support interactions (OMSI) of supported platinum-group metal catalysts. Chemical Science 2018, 9 (32), 6679-6684.
16. Li, T.; Liu, F.; Tang, Y.; Li, L.; Miao, S.; Su, Y.; Zhang, J.; Huang, J.; Sun, H.; Haruta, M.; Wang, A.; Qiao, B.; Li, J.; Zhang, T., Maximizing the Number of Interfacial Sites in Single-Atom Catalysts for the Highly Selective, Solvent-Free Oxidation of Primary Alcohols. Angew. Chem. Int. Ed. Engl. 2018, 57 (26), 7795-7799.
17. Chen, F.; Jiang, X.; Zhang, L.; Lang, R.; Qiao, B., Single-atom catalysis: Bridging the homo- and heterogeneous catalysis. Chinese Journal of Catalysis 2018, 39 (5), 893-898.
18. Tang, H.; Su, Y.; Zhang, B.; Lee, A. F.; Isaacs, M. A.; Wilson, K.; Li, L.; Ren, Y.; Huang, J.; Haruta, M.; Qiao, B.; Liu, X.; Jin, C.; Su, D.; Wang, J.; Zhang, T., Classical strong metal-support interactions between gold nanoparticles and titanium dioxide. Sci Adv 2017, 3 (10), e1700231.
19. Tang, H.; Wei, J.; Liu, F.; Qiao, B.; Pan, X.; Li, L.; Liu, J.; Wang, J.; Zhang, T., Strong Metal–Support Interactions between Gold Nanoparticles and Nonoxides. Journal of the American Chemical Society 2016, 138 (1), 56-9.
20. Tang, H.; Liu, F.; Wei, J.; Qiao, B.; Zhao, K.; Su, Y.; Jin, C.; Li, L.; Liu, J.; Wang, J.; Zhang, T., Ultrastable Hydroxyapatite/Titanium-Dioxide-Supported Gold Nanocatalyst with Strong Metal–Support Interaction for Carbon Monoxide Oxidation. Angew. Chem. Int. Ed. 2016, 55 (36), 10606-11.
21. Lang, R.; Li, T.; Matsumura, D.; Miao, S.; Ren, Y.; Cui, Y. T.; Tan, Y.; Qiao, B.; Li, L.; Wang, A.; Wang, X.; Zhang, T., Hydroformylation of Olefins by a Rhodium Single-Atom Catalyst with Activity Comparable to RhCl(PPh3 )3. Angew. Chem. Int. Ed. 2016, 55 (52), 16054-16058.
22. Qiao, B.; Liu, J.; Wang, Y.-G.; Lin, Q.; Liu, X.; Wang, A.; Li, J.; Zhang, T.; Liu, J., Highly Efficient Catalysis of Preferential Oxidation of CO in H2-Rich Stream by Gold Single-Atom Catalysts. ACS Catalysis 2015, 5 (11), 6249-6254.
23. Qiao, B.; Lin, J.; Wang, A.; Chen, Y.; Zhang, T.; Liu, J., Highly active Au1/Co3O4 single-atom catalyst for CO oxidation at room temperature. Chinese Journal of Catalysis 2015, 36 (9), 1505-1511.
24. Qiao, B.; Liang, J.-X.; Wang, A.; Xu, C.-Q.; Li, J.; Zhang, T.; Liu, J. J., Ultrastable single-atom gold catalysts with strong covalent metal-support interaction (CMSI). Nano Research 2015, 8 (9), 2913-2924.
25. Qiao, B.; Wang, A.; Li, L.; Lin, Q.; Wei, H.; Liu, J.; Zhang, T., Ferric Oxide-Supported Pt Subnano Clusters for Preferential Oxidation of CO in H2-Rich Gas at Room Temperature. ACS Catalysis 2014, 4 (7), 2113-2117.
26. Qiao, B.; Wang, A.; Yang, X.; Allard, L. F.; Jiang, Z.; Cui, Y.; Liu, J.; Li, J.; Zhang, T., Single-atom catalysis of CO oxidation using Pt1/FeOx. Nat Chem 2011, 3 (8), 634-641.