Chemistry and Chemical Engineering
LI Changzhi
Title: Professor
Subject: Industrial Catalysis
Phone: 0411-84379738
Email: licz@dicp.ac.cn
Website:
Research Interests

Catalytic biomass conversion, valorization of lignin into chemicals and fuels, ionic liquid-mediated green process, bio-based fine chemicals.

 

1. Design and synthesis of advanced catalytic materials for biomass conversion, particularly lignin valorization.

2. New routes for the conversion of biomass to value-added products, such as heteroatom-participated lignin depolymerization for the generation of benzylamines, pyrimidines, quinoxalines, quinolines, etc. 

3. Ionic liquid mediated biomass conversion, such as cellulose hydrolysis and upgrading of bio-based platform compounds.

Biography
Professor, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS), 2019/07 - present
Associate Professor, Dalian Institute of Chemical Physics, CAS, 2012/08 - 2019/06
Assistant Professor, Dalian Institute of Chemical Physics, CAS, 2009/01 - 2012/07
Ph.D. in Organic Chemistry, Dalian Institute of Chemical Physics, CAS, 2005/09 - 2009/01
M.S., in Organic Chemistry, Hunan Normal University, 2002/09 - 2005/06
B.S. in Chemistry Education, Hunan Normal University, 1998/09 - 2002/06
Honors and Awards
Distinguished Lectureship Award of 11th Chinese Chemical Engineering Young Scholars' Symposium, 2022
ACS Publication Awards, 2019
Second Prize of Natural Science Award of Liaoning province, 2018
First Prize of Dalian Technological Invention, 2014
Min Enze Energy and Chemical Engineering Award, 2013
Publications

1. Zhang B., Guo T., Li Z., Kühn F. E., Lei M., Zhao Z., Xiao J., Zhang J., Xu D., Zhang T., Li C.* Transition-metal-free synthesis of pyrimidines from lignin β-O-4 segments via a one-pot multi-component reaction. Nat. Commun. 2022, 13, 3365.

2. Wan K., Tian B., Zhai Y., Liu Y., Wang H., Liu S., Li S., Ye W., An Z.*, Li C.*, Li J., James T. D., Chen Z.*, Structural materials with afterglow room temperature phosphorescence activated by lignin oxidation, Nat. Commun. 2022, 13, 5508.

3. Ding Y., Guo T., Li Z., Zhang B.*, Kühn F., Liu C., Zhang J., Xu D., Lei M.*, Zhang T., Li C. *, Transition-Metal-Free Synthesis of Functionalized Quinolines by Direct Conversion of β-O-4 Linkages, Angew. Chem. In. Ed. 2022, e202206284.

4. Li T., Chen B., Cao M., Ouyang X.*, Qiu X., Li. C.*, Constructing single-atom Ni on N-doped carbon via chelation-anchored strategy for the hydrogenolysis of lignin. AIChE J. 2022, e17877.

5. Diao X.; Ji N.*; Li X.; Rong Y.; Zhao Y.; Lu X.; Song C.; Liu C.; Chen G.; Ma L.; Wang S.; Liu Q.; Li, C.*, Fabricating High Temperature Stable Mo-Co9S8/Al2O3 Catalyst for Selective Hydrodeoxygenation of Lignin to Arenes. Appli. Catal. B: Environ. 2022, 305, 121067.

6. Jia Z.; Ji N.*; Diao X.; Li, C.*, et al. Highly Selective Hydrodeoxygenation of Lignin to Naphthenes over Three-Dimensional Flower-like Ni2P Derived from Hydrotalcite. ACS Catal. 2022. 12, 1338-1356.

7. Wu K.; Li X.; Wang W.*; Li, C.*, et al. Creating Edge Sites within the Basal Plane of a MoS2 Catalyst for Substantially Enhanced Hydrodeoxygenation Activity. ACS Catal. 2022, 12, 8-17.

8. Li X.; Ding Y.; Zhang B.*; Liu X.; Li, C.*, et al. Scission of C–O and C–C linkages in lignin over RuRe alloy catalyst, J. Energy Chem. 2022, 67 492–499.

9. LiuY.; Luo Q.; Qiang Q.; Wang H.; Ding Y.; Wang C.; Xiao J.; Li C.;* Zhang T. Successive Cleavage and Reconstruction of Lignin β-O-4 Models and Polymer to Access Quinoxalines, ChemSusChem, 2022, e202201401.

10. Zhang B., Guo T., Liu X., Kuhn F., Wang C., Zhao Z., Xiao J., Li C.*, Zhang T. Sustainable production of benzylamines from lignin, Angew. Chem. In. Ed., 2021, 60 (38), 20666-20671.

11. Wu K., Wang W., Guo H., Yang Y., Huang Y., Li W., Li C.*; Engineering Co Nanoparticles Supported on Defect MoS2-x for Mild Deoxygenation of Lignin-Derived Phenols to Arenes, ACS Energy Lett., 2020, 5(4): 1330-1336.

12. Jiang L., Guo H., Li C.*, Zhou P., Zhang Z.* Selective cleavage of lignin and lignin model compounds without external hydrogen, catalyzed by heterogeneous nickel catalysts, Chem. Sci., 2019, 10, 4458-4468.

13. Dai T., Li C.,* Lin L., Zhao Z., Zhang B., Cong Y., Wang A.* Selective Production of Renewable para-Xylene by Tungsten Carbide Catalyzed Atom-Economic Cascade Reactions, Angew. Chem. In. Ed., 2018, 57, 1808 –1812.

14. Guo, H. W.;  Miles-Barrett, D. M.;  Neal, A. R.;  Zhang, T.;  Li, C.*; Westwood, N. J.*, Unravelling the Enigma of LigninOX: Can the Oxidation of Lignin be Controlled? Chemcial Science 2018, 9, 702-711.

15. Li C., Zhao X., Wang A., Huber G. W., Zhang T.* Catalytic transformation of lignin for the production of chemicals and fuels, Chem. Rev. 2015, 115 (21), 11559-11624.