Chemistry and Chemical Engineering
FENG Siquan
Title: Associate Professor
Subject: Catalytic Chemistry,Chemical Engineering,Molecular Reaction Dynamics
Phone:
Email: siquan@dicp.ac.cn
Website:
Research Interests
Single-site or multi-site catalysis, carbonylation reactions, reaction mechanism, catalysis industrial engineering amplification
1. Single-site catalysis, two-site collaborative series catalysis, or three-sites and other multi-site collaborative catalysis. 
2. Metal nanoscale, cluster, single atom catalysts sulfur promotion/sulfur poisoning/sulfur poisoning reversible recovery study. 
3. Methanol carbonylation to acetic acid and methyl acetate; Carbonylation of methyl acetate to acetic anhydride; Synthesis of methyl acrylate from methyl acetate hydroxyl aldehyde. 
4. Propionic acid from ethylene mono-carbonylation catalyzed by single atom; Monocarbonylation of acetylene to acrylic acid or butenediic acid; Dimethyl butenediate from dicarbonylation of acetylene; Acetylene monocarbonylation to methyl acrylate, acrylamide; Propylene carbonylation to isobutyric acid, isobutyric acid dimerization to cyclobutanedione rehydrogenation to cyclobutanediol and other high value-added environmental protection polyester monomers. 
5. Hydrogenation of dimethyl oxalate to methyl glycolate or coupling of dehydrogenation to olefin such as ethanol and ethane propane to produce high value-added chemicals. 
6. Oxidative carbonylation of methane and carbonylation of carbon dioxide instead of carbon monoxide. 
7. Dimethyl carbonate from methanol carbon dioxide. 
8. Single/double polyatomic catalytic carbonyl conversion to alcohols, aldehydes, acids, esters, amines (methanol, ethanol, ethylene glycol, glycerol, butanediol, pentanediol, hexanediol, butanediol; Acetic acid, propionic acid, succinic acid, adipic acid; Methyl acetate, ethyl acetate; Ethylene diamine, propylene diamine, butyldiamine, hexenediamine, ethanolamine, acrylamide). 
9. Basic research +DFT theoretical calculation +Aspen chemical simulation. 
10. Basic research → laboratory test → pilot test (single tube or kettle) → industrial model test → industrialization
Biography
Education 2014/08 -- 2019/11, President of Student Union, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Doctor of Engineering. 
2013/09 -- 2014/07, Monitor, University of Chinese Academy of Sciences (Yuquan Campus), Postgraduate Learning. 
2009/09 -- 2013/06, Monitor/President of Youth Association, Yunnan University, Bachelor of Engineering 
2005/08 -- 2009/06, Monitor, Senior High School of Liupanshui No. 3, Middle School 
1995/08 -- 2005/07, Monitor, Dahe Central School of Zhongshan District, Junior High School
Honors and Awards
1. Member of Youth Innovation Promotion Association, Chinese Academy of Sciences, 2022 
2. Top 100 Excellent Doctoral Dissertation Award, Chinese Academy of Sciences, 2021 
3. Excellent Doctoral Graduates of Chinese Academy of Science University, Institute (School), 2021 
4. Excellent Doctoral Graduates of Beijing, Municipal and Prefecture-level, 2020 
5. Outstanding young doctoral talents of Dalian Institute of Chemical Physicals, CAS, 2019 
6. National Scholarship, National Level, 2019 
7. Tang Lixin Scholarship, Institute (School), 2019 
8. Lin Liwu Outstanding Doctoral Scholarship, Institute (School), 2019 
9. Excellent Communist of Chinese Communist Party, Institute (School), 2019 
10. Merit Student Model of University of Chinese Academy of Sciences, Institute (School), 2018 
11. Excellent Student Cadre of University of Chinese Academy of Sciences, Institute (School), 2015 
12. Outstanding Student Cadre of Yunnan Province, Provincial, 2012
Publications
1. Feng, Siquan#; Song, Xiangen#*; Liu, Yang#; Lin, Xiangsong*; Yan, Li; Liu, Siyue; Dong, Wenrui; Yang, Xueming; Jiang, Zheng*; Ding, Yunjie*; In situ formation of mononuclear complexes by reaction-induced atomic dispersion of supported noble metal nanoparticles. Nat. Commun. 2019, 10 (1), 5281. 
2. Xingju, Li#; Feng, Siquan#; Patrick, Hemberger; Andras, Bodi; Song, Xiangen*; Qiao, Yuan; Jiali, Mu; Li, Bin; Jiang, Zheng; Ding, Yunjie*; Iodide-Coordinated Single-Site Pd Catalysts for Alkyne Dialkoxycarbonylation. ACS. Catal. 2021, 11, 9243-9251. 
3. Yuan Qiao#; Gu Yating#, Feng, Siquan; Song, Xiangen*; Jiali, Mu; Li, Bin; Li, Xingju; Cai, Yutong; Jiang, Miao; Yan, Li; Jingwei, Li; Jiang, Zheng; Wei, Yingxu; Ding, Yunjie*; Sulfur-Promoted Hydrocarboxylation of Olefins on Heterogeneous Single-Rh-Site Catalysts. ACS. Catal. 2022, 12, 7, 4203-4215. 
4. Feng, Siquan#; Lin, Xiangsong#; Song, Xiangen*; Binbao, Mei; Jiali, Mu; Jingwei, Li; Yang, Liu; Jiang, Zheng*; Ding, Yunjie*; Constructing Efficient Single-Rh-Sites on Activated Carbon via Surface Carbonyl Groups for Methanol Carbonylation. ACS. Catal. 2021, 11(2), 682-690. 
5. Feng, Siquan; Hemberger, Patrick; Bodi, Andras; Song, Xiangen*; Yu, Tongpo; Jiang, Zheng; Liu, Yang; Ding, Yunjie*; Preparation and Regeneration of Supported Single-Ir-site Catalysts by Nanoparticle Dispersion via Nascent I Radicals. J. Catal. 2020, 382, 347-357. 
6. Feng, Siquan#; Lin, Xiangsong#; Song, Xiangen*; Liu, Yang; Jiang, Zheng; Hemberger, Patrick; Bodi, Andras; Ding, Yunjie*; The Role of H2 on the Stability of the Single-Metal-Site Ir1/AC Catalyst for Heterogeneous Methanol Carbonylation. J. Catal. 2020, 381, 193-203. 
7. Feng, Siquan#; Lin, Xiansong#; Song, Xiangen*; Liu, Yang; Jiang, Zheng; Ding, Yunjie*; Insight into the stability of binuclear Ir–La catalysts for efficient heterogeneous methanol carbonylation. J. Catal. 2019, 377, 400-408. 
8. Feng, Siquan; Song, Xiangen*; Ren, Zhou; Ding, Yunjie*; La-stabilized, single-atom Ir/AC catalyst for heterogeneous methanol carbonylation to methyl acetate. Ind. Eng. Chem. Res. 2019, 58 (12), 4755-4763. 
9. Yu, Zhipeng#; Xu, Junyuan#; Feng, Siquan#; Song, Xiangen; Bondarchuk, Oleksandr; Faria, Joaqim L.; Ding, Yunjie; Liu, Lifeng*; Rhodium Single-atom Catalysts with Enhanced Electrocatalytic Hydrogen Evolution Performance. New J. Chem. 2021, 45, 5770-5774. 
10. Li, Bin; Song, Xiangen*; Feng, Siquan; Yuan, Qiao; Jiang, Miao; Yan, Li; Ding, Yunjie*; Direct Conversion of Methane to Oxygenates on Porous Organic Polymers Supported Rh Mononuclear Complex Catalyst under Mild Conditions. Appl. Catal. B: Environ. 2021, 293, 120208. 
11. Yuan, Qiao; Song, Xiangen*; Feng, Siquan; Jiang, Miao; Yan, Li; Ding, Yunjie*; An Efficient and Ultrastable Single-Rh-Site Catalyst on a Porous Organic Polymer for Heterogeneous Hydrocarboxylation of Olefins. Chem. Comm. 2021, 57(4), 472-475. 
12. Li, Jinlei; Li, Cunyao; Feng, Siquan; Zhao, Ziang; Zhu, Hejun; Ding, Yunjie*; Atomically Dispersed Zn-Nx Sites in N-Doped Carbon for Reductive N-formylation of Nitroarenes with Formic Acid. ChemCataChem. 2020, 12 (6), 1546-1550. 
13. Ren, Zhou; Liu, Yang; Lyu, Yuan*; Song, Xiangen; Zheng, Changyong; Feng, Siquan; Jiang, Zhen; Ding, Yunjie*; Sing-Atom Rh Based Bipyridine Framework Porous Organic Polymer: A High Active and Suprerb Stable Catalyst for Heterogeneous Methanol Carbonylation. J. Catal. 2019, 369, 249-256. 
14. Ren, Zhou; Lyu, Yuan*; Feng, Siquan; Song, Xiangen; Ding, Yunjie*; Acid-Promoted Ir-La-S/AC Catalyzed Methanol Carbonylation on Single Atomic Active Sites. Chin. J. Catal. 2018, 39 (6), 1060-1069. 
15. Ren, Zhou.; Lyu, Yuan*; Feng, Siquan; Song, Xiangen; Ding, Yunjie*; A Highly Efficient Single Site Rh-POL-PPh3 Catalyst for Heterogeneous Methanol Carbonylation. Mol. Catal. 2017, 442, 83-88. 
16. Li, Cuiping;* Wang, Jiaqiang; Feng, Siquan; Liu, Zhan, Low-Temperature Synthesis of Crystalline Inorganic/Metallic Nanocr-Halloysite Composite Nanotubes. Chin. J. Chem. 2014, 32 (7), 599-606. 
17. Li, Cuiping;* Wang, Jiaqiang; Feng, Siquan.; Yang, Zhan; Ding, Sujiang, Low-Temperature Synthesis of Heterogeneous Crystalline TiO2-Halloysite Nanotubes and Their Visible Light Photocatalytic Activity. J. Mater. Chem. A 2013, 1 (27), 8045-8054. 
18. Liu, Chuanshui; Tai, Zhigang; Feng, Siquan; Fang, Yunshan; Cai, Le*; Ding, Zhongtao, Chemical Constituents from the Seed Coat of Juglans Regia. China J. Chin. Mater. Med. 2012, 37 (10), 1417-1421. 
19. Zheng, Changyong; Feng, Siquan; Song, Xiangen*; Ding, Yunjie*; Activated Carbon Supported Au-Cu Binary Catalyst for Heterogeneous Methanol Carbonylation. Shiyou Huagong/Petrochemical Technology, 2019, 48(12), 1191-1198.