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Visible Light-Induced Bifunctional Rhodium Catalysis Developed for Decarbonylative Coupling of Imides with Alkynes
  English.dicp.cas.cn    Posted:2020-10-29    From:Group 02T4

Carbonyl groups are ubiquitous in pharmaceuticals, natural products, and agricultural chemicals, especially amides. Transition metal-catalyzed decarbonylation offers a distinct synthetic strategy for new chemical bond formation and carbonyl groups transformation. However, the π-backbonding between CO π* orbitals and metal center d-orbitals impedes ligand dissociation to regenerate catalyst under mild condition.

Recently, a team led by Prof. CHEN Qing-an from the Dalian Institute of Chemical Physics (DICP) of the Chinese Academy of Sciences (CAS) developed a visible light-induced bifunctional rhodium catalysis for decarbonylative coupling of imides with alkynes under ambient conditions.

This study was published in Angew. Chem. Int. Ed. on Sep. 29.

Light-induced bifunctional rhodium catalysis for decarbonylation (Image by MIN Xiangting)

Initial mechanistic studies suggested that rhodium complex simultaneously served as the catalytic center and photosensitizer for decarbonylation. Under visible light irradiation, it generated the excited state Rh-complex where the transfer of an electron from the π-backbonding Rh-CO orbital into an antibonding orbital decreased the bond dissociation energy of the Rh–CO bond.

This visible light-promoted catalytic decarbonylation strategy offers new opportunities for carbonyl groups transformation.

This study was supported by National Natural Science Foundation of China, China Postdoctoral Science Foundation and Liaoning Revitalization Talents Program. (Text by MIN Xiangting)

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