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Dalian Coherent Light Source Revealed New Dissociation Channels in Ethane Photochemistry
  English.dicp.cas.cn    Posted:2020-06-10    From:Group 2503

Understanding and exploiting the environment of extraterrestrial bodies is a central objective of planetary science. The gas giants, such as Jupiter, Saturn, Uranus and Neptune, are rich in molecular chemistry and remain the target of prolonged scientific study.

Same as Earth, these planets orbits the sun with its own eccentricity and obliquity leading to seasonal variations in incident solar and thus a cycling chemical composition with latitudinal and altitudinal variations in the abundances of the various molecular constituents.

Recently, Prof. YUAN Kaijun and Prof. YANG Xueming’s group from the Dalian Institute of Chemical Physics (DICP) of the Chinese Academy of Sciences, in cooperation with Prof. Michael N. R. Ashfold from the University of Bristol and Prof. Christopher S. Hansen from the University of New South Wales, revealed the new dissociation channels in the ethane photochemistry by using Dalian Coherent Light Source (DCLS).

The absorption of near-infrared solar radiation by methane (CH4) is an important contributor to heating the upper atmospheres (stratospheres) of these planets. CH4 contributes less to stratospheric cooling, however, which is more reliant on emission from ethane (C2H6) and acetylene (C2H2).

Understanding the balance and interplay between CH4 and C2H6/C2H2 is central to understanding the atmospheric dynamics of the gas giants. Therefore, the photodissociation of ethane have been studied systematically based on DCLS.

The VUV photochemistry of ethane, which is an important constituent in the atmospheres of the gas giants, has been studied in the wavelength range from 112nm to 126 nm by using the free electron laser (FEL) and multi-mass imaging detection methods. The scientists demonstrated contributions from at least five primary photofragmentation pathways yielding CH2, CH3 and/or H atom products from ethane following VUV excitation.

These results point to several shortcomings in the description of ethane photochemistry used in contemporary models of the atmospheres of the gas giants and help rationalize hitherto unexplained aspects of the ethane/acetylene ratios observed in the Cassini-Huygens fly-by of Jupiter.

The results were published in Chemical Science. It was supported by the Strategic Priority Research Program of the Chinese Academy of Sciences, the Chemical Dynamics Research Center, and the National Natural Science Foundation of China. (Text by CHANG Yao)

The CH3, CH2 and H atom elimination channels in the photodissociation of ethane. (Image by CHANG Yao)

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